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Beilstein J. Org. Chem. 2012, 8, 1896–1900, doi:10.3762/bjoc.8.219
Graphical Abstract
Scheme 1: Typical generation of ylide 4 and reaction examples.
Scheme 2: Proposed ylide 4 formation from α-lithiated epoxide 10.
Scheme 3: Z-Allylic ester 6 from epoxide 11.
Scheme 4: E-allylic alcohol 7 from epoxide 11.
Scheme 5: E-allylic alcohol 7 and alkene 12 from epoxide 11 by using s-BuLi.
Scheme 6: Terminal alkene 14 from epoxide 13.